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Calcium Citrate
CAS Registry Number: [5785-44-4]
Chemical Formula: (C6H5O7)2Ca3 · 4H2O
E-Number: E333Chemical Data
Chemical Formula
Ca3(C6H5O7)2 · 4H2O
CAS Number
5785-44-4
Molecular Weight
570.50
Use
Nutrient; Dietary Supplement; Pharmaceuticals
Description
Fine, white granular with characteristic odor
Containers
50 kg / 110 lb. fiber drums; 25 kilogram packs EU only
Storage
Store in a clean, dry warehouse in the original unopened containers.
Revision Date
02/24/2009
Chemical Specifications
Tests
Specifications
Assay
97.5-100.5 %
Aluminum
5 ppm maximum
Fluoride
0.0025% maximum
Heavy Metals (as Pb)
0.002% maximum
LOD
10.0-13.3%
Arsenic
3 ppm maximum
Acid Insolubility
0.2 % maximum
Lead
10 ppm maximum
Residual Solvents
Conforms to USP
General Information
The most commonly used calcium salt of citric acid is tricalcium dicitrate tetrahydrate, hereinafter referred to as tricalcium citrate. In some countries such as USA, tricalcium citrate is simply denominated calcium citrate. It is produced by complete neutralization of citric acid with a high purity calcium source such as calcium hydroxide or calcium carbonate.
With its high calcium content of 21%, tricalcium citrate is the most economic calcium salt among the commonly used organic calcium salts.
Characteristics
Tricalcium citrate is supplied as a white, odourless, crystalline powder or fine powder. It is slightly soluble in water and freely soluble in diluted hydrochloric acid. In contrary to other salts, tricalcium citrate is better soluble at lower temperatures (so-called "inverse solubility"). It is practically insoluble in alcohol. Tricalcium citrate loses one molecule of water at 115-125°C, and 2 more molecules at 145-150°C and the last one at 175-185°C, while decomposing.
During heat treatment, it is less reactive than other calcium salts due to its inverse solubility. With regard to its significantly better bioavailability, tricalcium citrate is preferred over inorganic calcium sources such as calcium carbonate or calcium phosphate.
Main Functions / Properties
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Regulates pH in food and beverages
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Is a sequestering and stabilizing agent in food
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Controls the formation of alginate/pectin gels in food
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Is a firming agent for fruits and vegetables
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Supports heat stability of fruit fillings
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Is a cleaning agent in dentifrices
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Has a neutral taste
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Is less reactive during heat treatment than other calcium salts
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Is a highly bioavailable calcium source in pharmaceuticals, foods and beverages
Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from any source of heat or ignition. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Packing:
Calcium Citrate is available in 25/50 Kg Paper or HDPE Bags with inner liner.
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